So can do
dir \\servername\directorynamein your PowerShell script, before you do
Also, please attach a full session log file showing the problem (using the latest version of WinSCP).
To generate the session log file, set
Session.SessionLogPath. Submit the log with your post as an attachment. Note that passwords and passphrases not stored in the log. You may want to remove other data you consider sensitive though, such as host names, IP addresses, account names or file names (unless they are relevant to the problem). If you do not want to post the log publicly, you can mark the attachment as private.
Thank you Martin, Doing below two things in a windows scheduler for this particular batch, fixed this issue for me.
1. Unchecked "Run with Highest Privileges"
2. Select option "Run only when user is logged on"